مروری بر عوامل پخت تأخیری-گرمایی رزین اپوکسی

نوع مقاله : مروری

نویسندگان

1 مازندران، دانشگاه مازندران، دانشکده فنی و مهندسی، گروه مهندسی شیمی، صندوق پستی 13534-47416

2 تهران، پژوهشگاه پلیمر و پتروشیمی ایران، پژوهشکده فرایند، گروه کامپوزیت، صندوق پستی 112-14975

چکیده

رزین‌های اپوکسی به دلیل خواص فیزیکی و مکانیکی و نیز مقاومت گرمایی، الکتریکی و شیمیایی خوب، به‌طور گسترده در صنایع کامپوزیت، هوافضا، ساختمان، الکترونیک، چسب و پوشش به‌کار گرفته می‌شوند. رزین‌های اپوکسی برای پخت‌ به‌ مواد شیمیایی نیاز دارند که عوامل پخت یا سخت‌کننده نامیده می‌شوند. این مواد، شرایط فراورش و خواص نهایی سامانه رزین را تحت تأثیر قرار می‌دهند. در حالت کلی، عوامل پخت اپوکسی‌ها را می‌توان به دو گروه معمولی (پخت محیطی یا پخت گرمایی) و تأخیری دسته‌بندی کرد. افزودن عوامل پخت معمولی به رزین برای انجام واکنش‌های شبکه‌ای‌شدن حتی در دمای محیط، سبب افزایش تدریجی گرانروی می‌َشود و در نهایت رزین ژل شده و پخت می‌شود. اما، عوامل پخت تأخیری پس از افزوده‌شدن به رزین در دمای محیط واکنشی انجام نمی‌دهند و گرانروی آمیزه تغییر نمی‌کند، بنابراین، برای تهیه سامانه‌های تک‌جزئی رزین اپوکسی استفاده می‌شود. این عوامل پخت در شرایط معمول فعال نیستند و با رزین واکنشی نمی‌دهند. اما، با اعمال محرک خارجی مانند نور و گرما فعال می‌شوند. از آنجا که مهم‌ترین محرک خارجی گرماست، بنابراین عوامل پخت تأخیری از پرکاربردترین و رایج‌ترین عوامل پخت تأخیری-گرمایی هستند. عوامل پخت تأخیری-گرمایی شامل عوامل پخت تأخیری دارای هیدروژن فعال، کاتالیزی و محافظت‌شده با گروه‌های شیمیایی و میکروکپسولی‌‌ها هستند. عوامل پخت محافظت‌شده با گروه‌های شیمیایی عوامل پخت دارای هیدروژن فعال معمولی هستند که با گروه‌های شیمیایی محافظت می‌شوند. انتخاب نوع سامانه تأخیری موضوع مهمی بوده و بر شرایط فراورش و خواص نهایی رزین پخت‌شده بسیار اثرگذار است. در این مقاله آخرین یافته‌ها در این باره مرور شده است.

کلیدواژه‌ها


عنوان مقاله [English]

Thermally-Latent Curing Agents for Epoxy Resins: A Review

نویسندگان [English]

  • Sayed Morteza Mozaffari 1
  • Mohammad Hosain Beheshty 2
1 1. Department of Chemical Engineering, Faculty of Engineering, Mazandaran University, P.O. Box 47416-13534, Mazandaran, Iran
2 Department of Composites, Faculty of Processing, Iran Polymer and Petrochemical Institute, P.O. Box: 14975-112, Tehran, Iran
چکیده [English]

Epoxy resins are widely used in composites, aerospace, construction, electronic, adhesive and coatings industries due to their high physical and mechanical, thermal resistance, electrical and chemical properties. For curing epoxy resins, a chemical material, called curing agent or hardener, must be used. Curing agents have strong effect on the processing conditions and final properties of the cured resins. In general, epoxy curing agents can be classified in two groups of normal (room or high temperature) and latent curing agents. Normal curing agents increase the resin viscosity at room temperature due to crosslinking or curing reactions and the resin is gelled and finally cured. The rate of viscosity increment would be different and depends on the kind of curing agent. On the other hand, latent curing agents cannot react with epoxy resin at room temperature and do not increase the resin viscosity. Therefore, they are being used for preparing one-part epoxy resins. Latent curing agents are not active at room temperature, but they will react with epoxy resin by the application of an external force like heat or light. Thermally-latent curing agents are well-known and they are widely used. They include substances with active hydrogen, and are catalyzed and protected by chemical groups and microcapsules. Selection of a latent curing system for an application is an important issue which affects the processing conditions and final properties of the cured resins. In this paper, the latest achievements in this area are reviewed.

کلیدواژه‌ها [English]

  • epoxy resin
  • hardener
  • latent curing agent
  • composite
  • viscosity
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